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Because the reaction is exothermic, the product gases heat up and expand, and in turn can be harnessed to do work. In a fire, such as arson, this expansion generates plumes with predictable behaviors that leave distinctive markings at the crime scene.
Fire and arson investigators examine the physical attributes of a fire scene and identify and collect physical evidence from the scene. This evidence is then analyzed to help determine if the cause of the fire was accidental or deliberate.
The main steps of a fire investigation include: Arrive at the scene. Ensure safety of crime scene. Secure the area. Investigate the scene. Evaluate external structure. Evaluate interior structure. Document the evidence. Sample and tag evidence. Conclude the investigation. Finish necessary documents/reports.
The arson investigator observes the scene, collects and gathers physical evidence, and interviews witnesses. Using the information obtained, the arson investigator will determine if the fire was accidental or deliberate and identify a suspect.
Liquid items can be transported in non-breakable, leakproof containers. Arson evidence is usually collected in air-tight, clean metal cans. Only large quantities of dry powder should be collected and stored in plastic bags. Moist or wet evidence (blood, plants, etc.)
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Physical Evidence of Possible Arson Burn pattern: multiple origins or unusual origin location. Presence/absence, and/or condition of ignition key. Ignition lock/switch condition. Accelerants in unexpected location(s) Missing accessories, components, or personal property. Components that have been tampered with.
By contrast, a fire caused by accident or ordinary carelessness is not arson, because criminal intent is lacking. Nonetheless, reckless activityor burning without regard to consequencescan result in an arson conviction.
The first step in a fire investigation is the preliminary scene examination/size-up. For best results, a trained fire investigator should be notified about and respond to serious fires or possible arson fires immediately after fire apparatus is dispatched.

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