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The text discusses the relationship between Gibbs free energy (ΔG) and potential or voltage in an electrochemical cell. The equation ΔG = -nFΔE is explained, where n is the number of electrons transferred in the reaction, F is Faraday's constant, and ΔE is the reduction potential. The significance of each component of the equation is highlighted, with n representing the number of electrons transferred during the reaction. It emphasizes the importance of understanding these components in electrochemical reactions for calculating the energy output.