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In Photoshop, you can quickly export a single document as a PDF by going to File, then Save a Copy. In older versions, it might be labeled as Save As. In the newer versions, Save a Copy is where you need to go. Select Photoshop PDF as the format in the new window that appears, and you can give your file a name and choose the save location. This way, your file will be exported as a PDF when you click Save.