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How to Expand Year Log For Free

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to wrap up this chapter lets compute the change in entropy associated with the free expansion to do that were going to use the formula for the change in entropy associated with the reversible process even though we know that the free expansion is an irreversible process well be very careful to justify why were able to do this before we start maybe a quick reminder about the free expansion we have a gas thats trapped in the left container when the valve is opened the gas expands and eventually occupies both containers the expansion however is rapid and uncontrolled meaning that the gas is not in equilibrium as it expands therefore we do not have a reversible process and we cannot plot the transformation in a PV diagram and well get back to that but thats the free expansion as far as the experiment goes in addition weve said this previously the walls are rigid and therefore the gas can do no work it cannot deform one way or the other the walls of the containers and the walls of

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