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so weve seen now this equation that tells us the slope of one of these coexistence lines on a phase diagram that that equation is called the clapeyron equation and we can determine that slope if we know the enthalpy and the change in volume and the temperature of a phase transition so well see how that works with an example well take a substance that were fairly familiar with water so if i tell you that the heat of vaporization the molar enthalpy of vaporization or actually not vaporization well do fusion so the molar enthalpy of fusion when i melt solid water to make it liquid is 6 kilojoules per mole i can also tell you the molar volume of the liquid the molar volume of the solid probably the easiest way to think about those is we could look up pretty easily the density of the liquid you know the density of liquid is pretty close to one gram per cubic centimeter look up the density of solid the density of ice and then convert those densities to molar volumes relatively easily i