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The video discusses the concept of sigma p as an independent variable scale of electron donating or withdrawing power. It suggests correlating tabulated sigma p values with the logarithm of rate constants in new organic reactions. By varying substituents in a reaction and comparing rate constant ratios, one can observe the impact of sigma p on reaction rates. The correlation will not be perfect, except in the case of ionization of parasubstituted benzoic acid. Expect a correlation, not an exact relationship, when studying sigma p influence on reaction rates.
