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The video tutorial discusses the identification of signals in an HMR spectrum corresponding to different protons in a ketone molecule. Two different signals are observed, with one representing nine identical protons and the other representing three protons. Integration of the signals reveals that signal a corresponds to the nine protons, while signal b corresponds to the three protons. This is determined based on the area under the curve in the spectrum, which is proportional to the number of hydrogen atoms creating the signal. Signal a is located at one ppm.