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Polymorph A is the most thermodynamically stable form. It has the highest melting point and the slowest dissolution rate. Polymorph B has a somewhat lower melting point and is dissolved much faster.
Polymorph is a fascinating new type of material. It is perfect for hobbyists whether you are model making or prototyping. At room temperature it just as strong as a normal plastic but at 62 degrees C becomes soft and mouldable. It can be heated easily and quickly either with hot water or hairdryer.
X-ray crystallographic methods, which reflect differences in crystal structure, in most cases can be definitive in the identification and characterization of polymorphs, and whenever possible should be included in the analytical methods utilized to define a polymorphic system.
The primary analytical method to characterize polymorphs is x-ray diffraction. Other methods used include solid state NMR, Raman and NIR spectroscopy, and thermal methods such as DSC and TGA.
[38,39] Melting of polymorph was observed in the temperature range of 29 to 34C indicating a higher thermodynamic stability.
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4 Analytical techniques for studying and characterizing polymorphs and polymorphic transitions 4.1 Introduction. 4.2 Optical/hot stage microscopy. 4.3 Thermal methods. 4.4 X-ray crystallography.
Among these polymorphs, polymorph (=polymorph I) is the least stable, exhibiting the lowest melting temperature (290.5 K) while polymorph 1 (=polymorph VI) is the most stable, exhibiting the highest melting temperature (309.5 K).
Different polymorphs may display different physical properties, such as solubility, melting points, heats of fusion upon melting, density, hardness, crystal shape, and stability to moisture and light [66].

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