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in XPS analysis you will always see single Peak for S orbitals while there are two peaks for f orbitals so let me show you why there are two peaks this is a common nomenclature or notation for xpsp representations this n represent principal quantum number in this case it is equal to four this mean number of shell this L represent basically or oral angular momentum and for L we have this three for for f orbital we have L is equal to three and this J represent total angular momentum which is equal to l this is orbital momentum plus minus this is called spin spin angular momentum which is equal to plusus half this is not orbital this is basically spin so in one case here this when we add this two we Lo spin up so it give us this 7 by2 here and when we subtract