Electron shells and orbitalsThe periodic table (article)Khan 2025

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The 2-8-8-18 rule is an extension of the 2-8-8 rule that includes the fourth energy level. It describes the maximum number of electrons in the first four energy levels: 2 in the first, 8 in the second, 8 in the third, and 18 in the fourth. This rule applies to elements beyond the first 20 in the periodic table.
The commonly used long form of the periodic table is designed to emphasize electron configurations.
The electrons in an atom are arranged in shells that surround the nucleus, with each successive shell being farther from the nucleus. Electron shells consist of one or more subshells, and subshells consist of one or more atomic orbitals.
What is the relationship between the electron configuration of an element and the period in which that element appears in the periodic table? The period of an element can be determined from an elements electron configuration. An elements period corresponds to its highest occupied main energy level.
Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements, for describing the chemical bonds that hold atoms together, and in understanding the chemical formulas of compounds and the geometries of molecules.
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Electrons occupy different energy levels, or shells. Each shell can hold a maximum number of electrons. Moving through the elements. in the periodic table, each atom has one more electron than the last because the number of electrons is the same as the atomic number.
The filling of the shells and subshells with electrons proceeds from subshells of lower energy to subshells of higher energy. This follows the n + ℓ rule which is also commonly known as the Madelung rule. Subshells with a lower n + ℓ value are filled before those with higher n + ℓ values.

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