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Chemical reactivity is understood both as the ability of individual molecules to take part in various chemical reactions and the study of rates of such reactions, that is equilibrium and rate processes. From: Chemical Kinetics (Second Edition), 2021.
Materials in this category include ammonium perchlorate, azides, organic peroxides, dry picric acid, picrate salts, crystalized perchloric acid and triazines. Reactive chemicals are classified as explosives, strong oxidizing agents, water reactives, air reactives, and special organic compounds.
Miscellaneous items (like batteries, mercury thermometers and florescent light bulbs) Flammable products (like kerosene, home heating oil, propane tanks and lighter fluid) Workshop or painting supplies (such as paint thinners and turpentine) Lawn and garden products (like herbicides and insecticides)
They can cause explosions, fires or extreme heating, with potential for significant personal injury and property damage. These materials are not commonly used in workplaces because of their hazards. When used, they must be handled and stored in stringently controlled conditions.
Examples of these products are ethyl acrylate, vinyl chloride, ethylene oxide, picric acid and anhydrous aluminum chloride. The symbol for dangerously reactive materials is a picture of a test tube with sparks or lines coming out of the tube surrounded by a letter R inside a circle.

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Examples of highly reactive chemicals are explosives, peroxides, water-reactives, and pyrophorics. All work involving highly reactive chemicals should be approved by the laboratory supervisor before initiation of the work.
Highly reactive materials encompass (but are not limited to): Air-reactive chemicals (e.g., palladium or platinum on carbon, platinum oxide, Raney nickel) Metal hydrides (e.g., lithium aluminum hydride, sodium borohydride) Cryogenic materials/liquefied gas, supercritical fluids (e.g., oxygen, nitrogen, helium)