SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03 03 2004 Date Updated: 03 05 2003 Version 1-2025

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Manufacturers and importers of hazardous chemicals must review and update the information in an SDS every 5 years. All SDS must list the date when it was last reviewed and updated. This date is usually written in Section 16 Any other relevant information, of the SDS.
Find chemical safety data sheets (SDS), formerly known as material safety data sheets, on fishersci.com using our SDS search. Click the Document and Certificates and then Safety Data Sheets links from the hamburger menu at the top left of the page.
Do Safety Data Sheets Expire? SDS sheets do not have a predetermined expiration date but must be updated whenever new and docHub information about the chemical becomes available. Examples of such information include: Updated hazard classifications.
Under WHMIS law, an MSDS for a controlled product must not be more than three years old. If you are still using a product that you bought more than three years ago, you may not have a current MSDS. Contact the manufacturer or supplier again and ask for a newer version of the MSDS.
This definition means that an SDS must be updated when new information changes how the hazardous product is classified or when you change how you will handle, store, or protect yourself from its hazards. SDSs must be updated within 90 days of the supplier becoming aware of the new information.
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