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Exemption certificates are signed by purchasers and are given to sellers to verify that a transaction is exempt. Sellers should exclude from taxable sales price, the transactions for which they have accepted an exemption certificate from a purchaser as described below.
To apply for exempt status, the State of Wisconsin requires that you complete Wisconsin Department of Revenue Form S-211 (Wisconsin Sales and Use Tax Exemption Certificate). The effective date of the sales tax exemption is the date the form is signed.
Exemption certificates are signed by purchasers and are given to sellers to verify that a transaction is exempt. Sellers should exclude from taxable sales price, the transactions for which they have accepted an exemption certificate from a purchaser as described below.
(a) Continuous or blanket exemption certificates do not expire and need not be renewed at any prescribed interval. However, they should be renewed at reasonable intervals in case of a business change, registration number change, or discontinuance of the specific business claiming the exemption.
Tax-exempt organizations are generally required to have and use an employer identification number (EIN). Tax-exempt organizations must use their EIN if required to file employment tax returns or give tax statements to employees or annuitants.

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Exemption certificate instructions can be found here: S-211 Instructions. For questions or assistance, please contact DOR Customer Service Bureau at (608) 266-2776 or DORSalesandUse@wisconsin.gov. Check one of the following: Single Purchase - Check if this certificate is for a single purchase only.
How do I obtain a permit? You can register online or complete an Application for Business Tax Registration and fax or mail it to the department.
Apply for a CES number by completing Form S-103, Application for Wisconsin Sales and Use Tax Certificate of Exempt Status. Include a copy of your organization's 501(c)(3) determination letter from the IRS.
Send a Certificate of Exemption information can be sent to Wisconsin Public Service Customer Service, P.O. Box 19001, Green Bay, WI 54307-9001 or fax it to 800-305-9754. Prior to sending in your certificate of exemption. Please review our certificate of exemption checklist.
Only certain services sold, performed, or furnished in Wisconsin are subject to Wisconsin sales or use tax. Taxable services include: Admission and access privileges to amusement, athletic, entertainment, or recreational places or events. Access or use of amusement devices.

wisconsin tax exempt form instructions