Substitution vs elimination chart 2025

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Elimination means removal. So, a reaction in which only the removal of atoms takes place is called an elimination reaction. Substitution means replacing one thing with another. Such a reaction, in which an atom or group is replaced by other atoms is called a substitution reaction.
The substitution reaction is defined as a reaction in which the functional group of one chemical compound is substituted by another group or it is a reaction which involves the replacement of one atom or a molecule of a compound with another atom or molecule.
Higher temperatures encourage elimination. Higher concentrations favour elimination. For a given halogenoalkane, to favour elimination rather than substitution, use: heat.
In a substitution reaction an existing group on the substrate is removed and a new group takes its place. In an elimination reaction the group is simply removed and no new group comes to take its place and this usually results in a double or triple bond forming in the substrate instead.
So, the major difference between the substitution and elimination method is that the substitution method is the process of replacing the variable with a value, whereas the elimination method is the process of removing the variable from the system of linear equations.
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Substitution means to substitute and elimination means to remove.

elimination vs substitution pdf