Work in TIN in XPS

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Aug 6th, 2022
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How to work in TIN in XPS

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good afternoon my name is Ben Schmitt staff scientist at physical electronics today Iamp;#39;ll be discussing how to characterize the electronic band structure using ups and lifeamp;#39;s as options on the versa probe three multi technique XPS system to motivate this work I want to show the schematic of a basic opto electronic device which could be something like a photovoltaic solar cell or a light-emitting diode for a flat panel display these devices typically consist of multiple layers and each layer has a specific function for how it handles electrons and holes to produce the desired outcome when designing such a device we need to know what the electrical parameters of each of the individual component layers are often we will reference energy to the vacuum level and then we have several parameters we can use to define the behavior of each layer as shown here in the diagram on the Left I have a basic device consisting of two electrodes and two semiconducting layers the electrodes

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It is a quantitative spectroscopic technique which utilises core level shift to obtain information on the chemical and electronic state of a samples elemental components to a penetration depth of ~ 10-100 . When a photon of energy (h) penetrates the surface of a solid it is absorbed by an electron.
The blue curve indicates a 5-year derivative. The strength of the XPS technique relies on that the chemical environment of an atom has a pronounced effect on the assessed binding energies (BEs) of core-level electrons, the effect commonly referred to as the chemical shift [2].
This chemical shift is dependent on the electronegativity (electron withdrawing power) of atoms bonded to carbon. Oxygen having more electron withdrawing power than carbon or hydrogen results in an increase in the C-O binding energy relative to C-C. Multiple bonds to electronegative atoms as in O-C=O.
therefore, binding energy peak shifts positively. Conversely, if the electronegativity of the doping element is lower than the base element, the electron density around it increases and the binding energy decreases, leading a red shift in BE peak position.
Chemical shift arises in the initial state from the displacement of the electronic charge from the atom towards its ligands, reducing the electrostatic potential at the atom. There is a final state shift due to the polarization of the ligand by the core on the central atom.
The shifts in the XPS peak is related to its oxidation state and higher shift in binding energy corresponds to higher oxidation state. Some times more shift with noise peak is related to the satellite peak or shake up and it is a case for only some metal or its oxide for example Ni or NiO.
The main cause of the peak shift in XPS spectra is mostly related to chemical shifts due to the presence or absence of the chemical states of the element having different formal oxidation state. And the intensity may also be changed bcos it is directly linked to the number of atoms in the respective chemical state.
The main components of an XPS system are the source of X-rays, an ultra-high vacuum (UHV) chamber with mu-metal magnetic shielding, an electron collection lens, an electron energy analyzer, an electron detector system, a sample introduction chamber, sample mounts, a sample stage with the ability to heat or cool the

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