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weamp;#39;re going to go through the fitting of the titanium 2p peak this is a sample of titanium apatite composite and as you can see thereamp;#39;s a number of different oxidation states that are present this is a good example for the transition metals it shows a number of things we have gonna have an asymmetric peak for the metal we have spin-orbit splitting going on and so we may have to deal with multiple it splitting for some of the states and so weamp;#39;re gonna go through those things this sample has already been charged corrected to 2 carbon 1 s set to 2 84.8 evie for adventitious carbon so weamp;#39;re already done that the first thing weamp;#39;re going to do is create a background region go to components and we want to start adding in and sub components so the first thing weamp;#39;re going to put in is the spin-orbit doublets for the metallic peak so letamp;#39;s add two peaks and weamp;#39;ll just slide them around so that we theyamp;#39;re more where they shou