Void index in XPS smoothly

Aug 6th, 2022
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How to Void index in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from hig

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C1s spectra for polymers tend to have symmetric peak components. Extended delocalised electrons in a sample (e.g. aromatic rings) can result in satellite structure, several eV to higher binding energy of the main peak. -* satellite is seen 6eV from main C1s peak in polyethylene terephthalate, for example.
Carbon Non-Metals Primary XPS region: C1s.
This wide spread in C 1s peak position is independent of the time samples are exposed to ambient atmosphere, hence of the AdC layer thickness. This disturbing result shows that the commonly used referencing of XPS spectra against the C 1s peak of AdC is unreliable.
Binding energy of C1s electrons are usually detected around 285 eV, which is variable with the chemical state of carbon. Binding energies of common chemical states of carbon compounds with oxygen (Table 3.4) are used to distinguish graphene from graphite, graphene oxide, or reduced graphene oxide (Fig. 3.7).
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
Hydrogen has no core electrons and, therefore, coreelectron XPS is impossible. The H 1s electrons are valence electrons and as such participate in chemical bonding. Any signal from hydrogen would overlap with signals from excitation of valence electrons from other surface atoms.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.

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