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By now we have become somewhat familiar with transition metal complexes, but before examining the reactions they can participate in, we need to discuss a few more of their properties. First let us recall some of the theories we know regarding chemical bonding and molecular geometry. Way back at the beginning of general chemistry we learned about VSEPR theory, and the repulsion between electron clouds that determines the geometries of simple molecules. We also discussed crystal field theory, and the complications that arise when looking at transition metal complexes which utilize d orbitals. We saw that the five d orbitals in a given energy level are no longer degenerate when coordinating to ligands, because some of these orbitals sit on axes which accommodate the metal-ligand bonds, whereas some orbitals sit between these axes. So we introduced the concept of t2g orbitals, which are the lower-energy dxy, dxz, and dyz orbitals, and the higher-energy eg orb
