Strike chart in XPS smoothly

Aug 6th, 2022
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How to strike chart in XPS with top efficiency

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How to Strike chart in XPS

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this video is an introduction to xps xps is most often viewed through the analysis of xps data which involves using software to work out quantification and chemical state information based on spectra that are gathered from samples but to properly understand how the sample is analyzed in terms of the software its important to have some appreciation of the xps technique itself so this involves having an understanding of what were looking at in terms of energy spectra and also how spectra are acquired that will then be processed to produce the information that were after an xps spectrum is an energy spectrum and the energy spectrum is acquired by changing the energy at which we sample the number of electrons that arrive at a detector and as a consequence of these types of measurements we can create a histogram of intensity as a function of energy here its plotted as intensity as a function of binding energy and the binding energy is related to an electronic configuration with an atom

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Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
Carbon satellites in physics and spectroscopy, are small peaks that can be seen shouldering the main peaks in the nuclear magnetic resonance (NMR) spectrum.
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.
Definition of Satellite Peak: The term Satellite Peak is used to identify Plasmons, Shake-ups, Energy Loss, and various Un-identified Peaks.
Chemical Shifts Such shifts are readily observable and interpretable in XP spectra (unlike in Auger spectra) because the technique is of high intrinsic resolution (as core levels are discrete and generally of a well-defined energy) and is a one electron process (thus simplifying the interpretation).
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.
XPS is useful for quantitative analysis of surface composition and can detect all elements with the exception of hydrogen and helium through the detection of the binding energies of the photoelectrons. Small variations in binding energies of the photoelectron lines as well as Auger lines (see Section 16.5.
Page 25. Chemical Effects in XPS. Chemical shift: change in binding energy of a core electron of an element due to a change in the chemical bonding of that element.

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