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when a sample is analyzed by xps we typically measure a sequence of spectra and these often include a survey and a set of narrow scan regions and in this video what i would like to do is illustrate the importance of these additional data to the construction of a peak model for a specific photomission line in this case were going to look at the molybdenum 3d and fit these data with a set of components that require the use of additional information in order to extract useful information about the amount of molybdenum and these other elements within this sample the first question that needs to be answered is why do we need a peak model at all for this molybdenum and the survey spectrum provides the answer to that that is we see within the survey spectrum a docHub sulfur 2p peak and the problem is that because theres a sulphur 2p there must be a sulfur 2s and if we look at the element library and identify the sulphur peaks you can see that there ought to be a sulfur peak that is at