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hello friends welcome back to the series of photoemission spectra and in this video we will discuss about spin orbital coupling of xps data when we try to analyze the xps data we can see that some of the peaks show sharp single peak like in case of sodium 1s as shown here and in some cases the peak is split into two parts for example as in case of chlorine 2p this peak splitting is observed due to spin orbital coupling as the name suggests it is the coupling or interaction between spin and orbital motion of electron so lets first understand what is spin of electron speed spin is rotation of electron around its own axis and this rotation produces a magnetic field as shown here with the blue line now as electron is also revolving around the nucleus this angular motion also produces a magnetic field we can try to see this orbital motion in an alternate point of view where you can say that the nucleus is moving around the electron its the same thing but a different perspective so this m