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In this video tutorial, we explore the concept of spin-orbital coupling in XPS data analysis. Some peaks in XPS data exhibit single sharp peaks, while others show peak splitting, such as in the case of chlorine 2p. The splitting is explained by the interaction between the spin and orbital motion of electrons. Spin refers to the rotation of an electron around its own axis, which generates a magnetic field. This is in addition to the orbital motion of electrons around the nucleus. Viewing the orbital motion as the nucleus moving around the electron provides a different perspective on the same phenomenon.