Slide result in XPS smoothly

Aug 6th, 2022
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How to Slide result in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from hig

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XPS / ESCA The average depth of analysis for an XPS measurement is approximately 5 nm. PHI XPS instruments provide the ability to obtain spectra with a lateral spatial resolution as small as 7.5 m. Spatial distribution information can be obtained by scanning the micro focused x-ray beam across the sample surface.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
High-Resolution XPS (HR-XPS) uses a monochromator which provides the following advantages over a standard x-ray source: An x-ray energy distribution with reduced energy width improves chemical selectivity by narrowing the spectral peaks. A lower spectral background.
Its main features are: Highly automated instrument that uses focused monochromatic Al (K) X-rays for spatially resolved chemical analysis. X-ray spot size ranges from 10 m to 200 m.
The maximum sample size that can be analyzed in most XPS instruments is on the order of 20 cm2 and often on the order of a few cm2. Allowed sample heights are also instrument dependent, but typically are 25 mm.
X-ray photoelectron spectroscopy (XPS) is a surface analytical technique, which is based upon the photoelectric effect. Each atom in the surface has core electron with the characteristic binding energy that is conceptually, not strictly, equal to the ionization energy of that electron.
In most cases, XPS analysis samples many particles or many grains in a polycrystalline material, while EDX analysis may sample only one particle or one grain. EDX analysis may require many more sets of data to achieve an accurate average simply due to local sample inhomogeneity.
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.

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