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eventually the compound comes out of the end of the column the time from the start of the separation to the exit from the system is known as the retention time and this is described by TR the time is taken at the top of the peak the more interaction the component has with the stationary phase the longer the retention time if we go back to the airport analogy the retention time is simply the time it takes for the tourists from when they go through the security checkpoint to the entry onto the plane the retention time is very important in chromatography as we use this time to identify the component firstly we inject a known standard and identify its retention time in the chromatogram we then compare this time to a peak in the sample chromatogram if the time matches then there is a high probability of identifying the sample peak