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This video introduces XPS (X-ray Photoelectron Spectroscopy), a technique used to analyze data through software to gather quantification and chemical state information from spectra gathered from samples. Understanding the XPS technique is important to analyze samples accurately. XPS spectrum is an energy spectrum acquired by changing the energy to sample the number of electrons arriving at a detector. This data can be processed to produce the desired information by creating a histogram of intensity as a function of energy, plotted as intensity against binding energy related to an atom's electronic configuration.