Rework PII in XPS

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Aug 6th, 2022
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How to rework PII in XPS

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How to deconvolute XPS peak in origin

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Below are some common questions from our customers that may provide you with the answer you're looking for. If you can't find an answer to your question, please don't hesitate to reach out to us.
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How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
XPS is a powerful measurement technique because it not only shows what elements are present, but also what other elements they are bonded to. The technique can be used in line profiling of the elemental composition across the surface, or in depth profiling when paired with ion-beam etching.
The main cause of the peak shift in XPS spectra is mostly related to chemical shifts due to the presence or absence of the chemical states of the element having different formal oxidation state. And the intensity may also be changed bcos it is directly linked to the number of atoms in the respective chemical state.
Chemical shift arises in the initial state from the displacement of the electronic charge from the atom towards its ligands, reducing the electrostatic potential at the atom. There is a final state shift due to the polarization of the ligand by the core on the central atom.
X-ray photoelectron spectroscopy (XPS) determines the surface elemental composition. The technique consists of analyzing the emitted photoelectrons after X-ray irradiation of the sample.
Because XPS is a surface technique, there is a limited amount of organic information XPS can provide. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain.
XPS is a powerful quantitative technique for determining the electronic structure, elemental composition, and oxidation states of an element in a material.

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