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The video explains the concept of collateral debentures, which serve as additional security when a company takes out a loan. For instance, if XYZ Company wishes to raise a loan of 50 lakhs, it might pledge its machinery as primary collateral. In addition, the company can issue debentures worth 60 lakhs as further collateral to the bank. These debentures are only used by the bank if the company defaults on the loan. Thus, the debentures act as supplementary security beyond the initial asset pledged.