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This video provides an introduction to XPS, which is mainly analyzed through data collected using software to determine quantification and chemical state information from spectra gathered from samples. Understanding the XPS technique is crucial in knowing how the software analyzes the sample, involving energy spectra and acquisition methods to produce the desired information. An XPS spectrum is an energy spectrum acquired by changing the sampling energy to detect arriving electrons, resulting in intensity histograms plotted against binding energy related to an atom's electronic configuration.