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in this video were going to look at how charge compensation can influence an XPS measurement when we perform an XPS measurement the objective is to identify Peaks within the data that we can assign to binary energy and calculate the intensity of these Peaks so we can infer chemical State from both binding energy and relative intensities we must have confidence that these --piece are genuine Peaks and relate to the sample chemistry and not to the sample and how it was measured in order to investigate this a particular sample has been measured multiple times using different charge compensation state and acquisition conditions and by doing so we can observe how the structures within these data change as a result of the way these data were measured we can understand first of all whether we can trust the data and secondly how we would go about measuring a sample such as this one so that we can trust the data a photo emission peak represents a collection of electrons that have been emitted