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The video tutorial explores the linear Shirley background in detail. The basic Shirley background calculates a rise associated with the photoemission peak, but it may not be appropriate for certain materials, especially insulating ones. To accommodate variations, there are different forms of the Shirley background, including offset Shirley, extrapolate Shirley, and linear Shirley. The linear Shirley background is introduced to adjust the background for different peak structures, providing functionality related to the Shirley algorithm.