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hello friends so now we are starting a new series of videos on photo emission spectroscopy and if you dont want to miss any of our videos please subscribe to our channel and hit the bell icon so the basic principle of photoemission spectroscopy also known as xps is photoelectric effect which was discovered by albert einstein in 1905 for which he got the nobel prize also photoelectric effect says that when electromagnetic radiation such as light hits a material electrons from the surface are emitted out that means electrons can be ejected from the surface of material by just bombarding them with electromagnetic radiation or light important thing here is that the energy of photons of light should be higher than that of the binding energy of electrons because if photons of light are not having enough energy to remove electrons from the bind state to free state it wont work so the basic equation for the ejection of electrons from the surface by electromagnetic radiation becomes h nu is