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This video provides an introduction to XPS, which is primarily analyzed using XPS data and software to determine quantification and chemical state information. Understanding the XPS technique involves knowing how energy spectra are viewed and acquired, which helps in processing the data for analysis. An XPS spectrum is an energy spectrum obtained by varying the energy sampled to detect electrons, ultimately producing a histogram of intensity versus energy. Binding energy is related to the electronic configuration of an atom, contributing to the analysis of XPS data.