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The text discusses photoemission spectroscopy, focusing on the spectra obtained from the XPS instrument. It explains that the instrument plots kinetic energy versus the number of electrons counted, with the y-axis representing the number of electrons and the x-axis representing kinetic energy. In modern instruments, kinetic energy is converted to binding energy using a formula, resulting in lower kinetic energy corresponding to higher binding energy and vice versa. This shift in energy levels affects how the XPS spectra are interpreted.