Fix field in XPS smoothly

Aug 6th, 2022
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How to Fix field in XPS

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hello everyone thank you for joining us today today we have the pleasure of uh dr katerina artraskova giving us a talk on curve fitting in xps thank you john welcome everybody uh before we start the webinar i would like to highlight a recent series of xps guides that came out in journal of vacuum science and technology in recent years there has been acknowledged that a lot of literature there are a lot of um inconsistencies and mistakes related to xps analysis from the way we perform analysis to the way we that we do data analysis and that driven these series that are really excellent source of information from you and one of the papers that i was um working with the great team was the practical guides for graffiti in xps and that is the basis for todays webinar you can find lots and information in that guide that im not able to cover in details as much as i would love to due to time limitation so the outline were going to look first is what is the into our basis of xps or photoele

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The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
The ion gun is able to raster a 10 mm x 10 mm area of the surface at the recommended working distance. It is particularly suitable for depth profiling in XPS, ISS and SIMS. The ion gun can be also used for sample surface cleaning.
Shake-up satellites: distinct peaks a few eV below the main line. Shake-off satellites: broad feature at lower energy w.r.t. to main line. energy loss). n: e density, e: charge of e, m: mass of e electron.
The perturbation is called shake-up if they refer to an excitation in the final system, or shake-off if the result is the loss of one or more outer shell electrons from the ion.
Photoelectric Peaks, Auger Peaks and Energy Scales.
Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
Atoms present in compound being tested by XPS are determined ing to the equation: Here, binding energy is the energy of an electron attracted to a nucleus; photon energy is the energy of X-ray photons being used by the spectrometer, and the kinetic energy is the energy of the ejected electrons from the sample.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.

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