Finish PII in XPS smoothly

Aug 6th, 2022
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How to Finish PII in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from hig

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Among them, hydrogen cannot be detected by XPS because it has no core electrons.
The binding energies of the numerous photoelectrons emitted from a surface sample are used as a fingerprint to identify elements present. Chemical shifts in XPS spectra are observed when an element enters a different bound state, which results in changes in the binding energy of core electrons.
XPS is a surface sensitive technique because only those electrons generated near the surface escape and are detected. The photoelectrons of interest have relatively low kinetic energy.
Hydrogen has no core electrons and, therefore, coreelectron XPS is impossible. The H 1s electrons are valence electrons and as such participate in chemical bonding. Any signal from hydrogen would overlap with signals from excitation of valence electrons from other surface atoms.
Hence, the XPS spectrum maps the final states, i.e., energy differences between the ground state of the sample and the numerous final (or ionized) states.
XP spectra give evidence of functionalization and can provide insight into the identity of the functional groups.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
XPS is a surface sensitive technique because only those electrons generated near the surface escape and are detected. The photoelectrons of interest have relatively low kinetic energy.

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