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This video is the second part of a series on photoemission spectroscopy, building on the basic principles and instrumentation of XPS. The XPS instrument provides a plot of kinetic energy versus the number of electrons counted, with the y-axis representing the number of electrons and the x-axis representing kinetic energy. Modern instruments convert kinetic energy to binding energy using the formula h nu = binding energy + kinetic energy + phi. This results in a shift where lower kinetic energy corresponds to higher binding energy and higher kinetic energy corresponds to lower binding energy.