Finish pattern in XPS smoothly

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Aug 6th, 2022
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How to Finish pattern in XPS

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hello my name is jeff schalleberger and im going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thats exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thats what ill use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he did explaining this effect in 19

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How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
Photoelectric Peaks, Auger Peaks and Energy Scales.
Hence, the XPS spectrum maps the final states, i.e., energy differences between the ground state of the sample and the numerous final (or ionized) states.
The perturbation is called shake-up if they refer to an excitation in the final system, or shake-off if the result is the loss of one or more outer shell electrons from the ion.
Shake-up satellites: distinct peaks a few eV below the main line. Shake-off satellites: broad feature at lower energy w.r.t. to main line. energy loss). n: e density, e: charge of e, m: mass of e electron.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
Final State Effects: These describe the effect induced by the perturbation of the electronic structure resulting from photoelectron emission, particularly when core levels are involved.

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