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Aug 6th, 2022
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How to Finish information in XPS

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hello my name is jeff schalleberger and im going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thats exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thats what ill use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he did explaining this effect in 19

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X-ray photoelectron spectroscopy (XPS), also known as electron spectroscopy for chemical analysis (ESCA), is a technique for analyzing a materials surface chemistry. XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material.
In XPS, the atoms of the samples surface absorb X-rays and emit electrons, but in XRF the atoms of the sample both absorb and emit X-rays. In XRD, the atoms of the sample do not absorb X-rays at all, they just reflect them.
X-ray photoelectron spectroscopy (XPS), also known as electron spectroscopy for chemical analysis (ESCA), is a technique for analyzing a materials surface chemistry. XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material.
XPS is a surface sensitive technique because only those electrons generated near the surface escape and are detected. The photoelectrons of interest have relatively low kinetic energy.
Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.
How to Analyze XPS Spectra Data The X-Axis: Peak Position. The Y-Axis: Peak Intensity. Overlapping Peaks. More than One Elemental Peak. Analysis of Haze on a Polyimide Substrate. Passivation Integrity of Stainless Steel.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.

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