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This video provides an introduction to XPS, which is often analyzed through XPS data using software to quantify and determine chemical state information from gathered spectra. Understanding the XPS technique is key to analyzing samples properly, including appreciating energy spectra, acquisition methods, and processing for desired information. XPS spectrum is an energy spectrum acquired by changing energy to sample electrons arriving at a detector, leading to a histogram of intensity versus energy, plotted as intensity versus binding energy related to electronic configuration of an atom.