Fill in chapter in XPS

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Aug 6th, 2022
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How to fill in chapter in XPS

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hello my name is jeff schalleberger and iamp;#39;m going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thatamp;#39;s exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thatamp;#39;s what iamp;#39;ll use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he d

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The photoelectric effect occurs when an x-ray interacts with an electron in the matter. The photo is completely absorbed and its energy is transferred to an electron that is removed from the electron cloud.
The photoelectric effect is the dominant interaction for X rays with energies below 30 keV. This reaction results in the disappearance of the photon. The result is the ejection of a bound electron, usually from an inner shell, with a kinetic energy of hv EB, where EB is the original binding energy of the electron.
The chemical environment of an atom alters the binding energy (BE) of a photoelectron which results in a change in the measured kinetic energy (KE). The BE is related to the measured photoelectron KE by the simple equation; BE = h - KE where hv is the photon (x-ray) energy.
The photoelectric effect is the emission of electrons or other free carriers when light shines on a material. Electrons emitted in this way can be called photo electrons. This phenomenon is generally studied in electronic physics, as well as in fields of chemistry, such as quantum chemistry or electrochemistry.
Electrostatic fields within the hemispherical analyzer (HSA) are established to only allow electrons of a given energy (the so called Pass Energy PE ) to arrive at the detector slits and onto the detectors themselves. Figure 1:Logical layout for an XPS Instrument.
XPS detects all elements besides hydrogen and helium, so a survey scan is usually a starting point for most analyses. For each element, there is a range of electron states open to excitation by the x-ray beam.
Photoelectron spectroscopy simply applies the photoelectric effect to free atoms or molecules instead of metals. In PES, a sample is bombarded with high-energy radiation, usually UV or X-ray, which causes electrons to be ejected from the sample.
XPS physics - the photoelectric effect. can be thought of as an adjustable instrumental correction factor that accounts for the few eV of kinetic energy given up by the photoelectron as it gets emitted from the bulk and absorbed by the detector. It is a constant that rarely needs to be adjusted in practice.

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