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welcome back Im Matt chemist and today we have five important papers in organic synthesis for the month of March 2023. the first paper for today is this paper where they add cyclobutadiene to alkenes some highlights of this paper include a new protocol to prepare cyclobutadiene as previous methods for this were a little bit more harsh but the authors developed a new protocol which is milder Additionally the synthesis of bicyclic systems from cyclobuted ions was reported via a four plus two cycle Edition this enabled the synthesis of derivatizable cyclobutanes and the authors also reported the total synthesis of diphiperamide G in terms of the different approaches that were possible it had been reported that you could access it from this iron Tris carbonyl complex through an oxidative protocol unfortunately when this is formed it tends to dimerize in this endoselective fashion to what is essentially opened up cubane other chemistry can happen leading to the formation of other complex p