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This video introduces XPS, which is most commonly analyzed through XPS data using software to determine quantification and chemical state information from spectra gathered from samples. Understanding the XPS technique is essential for properly analyzing samples with the software, including energy spectra and acquisition methods. An XPS spectrum is an energy spectrum acquired by changing the energy for sampling electrons arriving at a detector, allowing the creation of intensity histograms plotted as intensity vs. binding energy related to atom electronic configuration.