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How to darken symbol in XPS

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Charles Zona (CZ): Hello, and welcome to another McCrone Group webinar. My name is Charles Zona, and today we are happy to welcome Doug Meier. Doug is going to talk to us about X-ray photoelectron spectroscopy, otherwise known as XPS. Before we get started I would like to give you a bit of Dougamp;#39;s background. Doug is a senior research scientist with McCrone Associates. He specializes in surface sensitive spectroscopies, such as Auger electron, X-ray photoelectron, infrared reflection absorption, thermal desorption, and low-energy electron diffraction. Doug was awarded the U.S. Department of Commerceamp;#39;s Silver Medal for his work in the development of conductometric chemical microsensor array technology for the detection of chemical warfare agents. He also has over ten years of micro beam analysis experience prior to joining McCrone Associates. Doug will field questions from the audience immediately following todayamp;#39;s presentation, and this webinar is being recorded

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What is the energy shift due to spin orbit splitting of the hydrogen 2p state?

(1) The 2p state is split into two states due to the spin-orbit coupling. E = -3.01884 x 10-5 eV for the 2 2P1/2 state The energy difference is 3∆ = 4.52826 x 10-5 eV.

What is 2p3 2 and 2p1 2?

The area ratio, or degeneracy, between these spin-orbit split peaks is then given by 2j + 1, or 1:2; This corresponds to 2 electrons in the 2p1/2 level and 4 electrons in the 2p3/2 level.

What is the kinetic energy equation for XPS?

XPS spectral lines are identified by the shell from which the electron was ejected (1s, 2s, 2p, etc.). The ejected photoelectron has kinetic energy: KE=hv-BE-! L electron falls to fill core level vacancy (step 1).

What is spin orbit splitting?

All orbitals except the s-orbitals (l = 0), yield a doublet with the two possible states having different binding energies this differece between the peaks is termed spin-orbit splitting (also known as j-j coupling).

What is the approximate thickness at which the XPS technique can provide chemical information?

X-ray photoelectron spectroscopy (XPS) is one of the most preferred tools that provides the chemical composition of material surfaces within 10 nm, along with elemental information and detection sensitivity of 0.1-1 at.

What frequency is the splitting due to spin-orbit interaction between the J 1 2 and J 3 2 levels of the 2p state of the hydrogen atom?

(c) Explain in physical terms where the Z4 dependence comes from. Show that the splitting due to spin-orbit interaction between the J= 3/2 and J= 1/2 levels of the 2p configuration in hydrogen is 11GHz.

What is the spin orbit coupling of 2p?

The magnitude of spin orbit coupling is different depending on whether the electron spin is parallel or anti-parallel to the orbital shell spin l, thus the two states possess different energies. In 2p electrons, L2 (total angular momentum j = l - s = 1/2) and L3 (total angular momentum j = l + s = 3/2) are formed.

What is the XPS characterization technique?

X-ray Photoelectron Spectroscopy (XPS) or Electron Spectroscopy for Chemical Analysis (ESCA) is a technique which analyzes the elements constituting the sample surface, its composition, and chemical bonding state by irradiating x-rays on the sample surface, and measuring the kinetic energy of the photoelectrons emitted

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Darken symbol in XPS with our multi-function editing solution

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Got questions?

What is the energy shift due to spin orbit splitting of the hydrogen 2p state?

What is 2p3 2 and 2p1 2?

What is the kinetic energy equation for XPS?

What is spin orbit splitting?

What is the approximate thickness at which the XPS technique can provide chemical information?

What frequency is the splitting due to spin-orbit interaction between the J 1 2 and J 3 2 levels of the 2p state of the hydrogen atom?

What is the spin orbit coupling of 2p?

What is the XPS characterization technique?

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