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This video provides an introduction to XPS, which is commonly analyzed through XPS data using software to quantify and provide chemical state information. Understanding the XPS technique is essential to properly analyze samples with software, including energy spectra and how spectra are acquired to produce the desired information. XPS spectra are energy spectra obtained by changing the energy at which electrons arrive at a detector, allowing for the creation of an intensity histogram as a function of binding energy related to electronic configuration.