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weamp;#39;re going to illustrate the linearly squares approach within cassa using this oxygen set of Spectra and you can see here this is the overlay of all the oxygen Spectra how the material oscillates between a silicon oxide and a titanium oxide and you can also see from this selection that has let me just illustrate that by holding the control key down and clicking you can see that the selection here represent a set of Spectra and these Spectra include from the titanium layer and a number that come from the Silicon layers and these clearly are moving around so a linearly squares applied to a silicon oxide layer in this particular experiment would not work well if we chose just a single Peak however the titanium will work reasonably well with with one representative Peak for the titanium so what we will do is we will find a titanium Peak and let me just see that that one is thatamp;#39;s the titanium that I was interested in whereas that one is a silicon so I think weamp;#39;ve n