Cut off emblem in XPS

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Aug 6th, 2022
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How to cut off emblem in XPS

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EXPLANATION: If a nucleus has more binding energy, it can hold the nucleus together more strongly which means the nucleus is more stable. So higher the binding energy, the more stable nucleus is.
In XPS, the atoms of the samples surface absorb X-rays and emit electrons, but in XRF the atoms of the sample both absorb and emit X-rays. In XRD, the atoms of the sample do not absorb X-rays at all, they just reflect them.
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
The more tightly bound a system is, the stronger the forces that hold it together and the greater the energy required to pull it apart.
Here, higher binding energies mean also higher oxidation states. This is known as chemical shift. A good starting point for a literature research for the peak shifts of your material is the XPS database of NIST:
The blue curve indicates a 5-year derivative. The strength of the XPS technique relies on that the chemical environment of an atom has a pronounced effect on the assessed binding energies (BEs) of core-level electrons, the effect commonly referred to as the chemical shift [2].
Chemical shifts in XPS spectra are observed when an element enters a different bound state, which results in changes in the binding energy of core electrons. In general, increased oxidation state (removal of valence electrons) increases the Binding Energy and addition of valence electrons decreases the Binding Energy.

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