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weamp;#39;re going to look at the fitting of the chromium 2p3 haves Peak and the big thing with the transition metals is that thereamp;#39;s something called multiplet splitting that can occur this happens when a a a compound or an ion has unpaired electrons so for example chromium 3 is 3 P6 3d3 so it has three unpaired Del electrons and what happens is when you get a Core electron vacancy made by photo ionization you get coupling between the unpaired electron in the core and the unpaired electrons in the outer shell and this shows up as a number of final states which you see in the photo electron Spectrum so instead of a nice single Peak for Chrome 3 we get this multiple split structure that shows can be fit with five Peaks actually in general the literature for chromium 2p has not been very good um thereamp;#39;s been many misinterpretations in the literature including some of the common databases which quote uh a single Peak bind energy for compounds that are known to have multip
