Correct index in XPS smoothly

Aug 6th, 2022
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How to Correct index in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from high

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Quantitative XPS is the process of comparing two or more intensities in XPS spectra to determine the amount of material at the surface of a sample. These intensities may be from the same peak or different peaks in the same spectrum or the same set of peaks in different spectra.
Definition of Satellite Peak: The term Satellite Peak is used to identify Plasmons, Shake-ups, Energy Loss, and various Un-identified Peaks.
X-ray photoelectron spectroscopy (XPS), also known as electron spectroscopy for chemical analysis (ESCA), is a technique for analyzing a materials surface chemistry. XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material.
The maximum sample size that can be analyzed in most XPS instruments is on the order of 20 cm2 and often on the order of a few cm2. Allowed sample heights are also instrument dependent, but typically are 25 mm.
XPS is used to provide information about the elemental composition of the coatings. The XPS spectrometer is used to obtain a survey spectrum, from which the elements present can be determined. Individual spectral peaks are then examined at higher energy resolution to give information on chemical state.
Highly automated instrument that uses focused monochromatic Al (K) X-rays for spatially resolved chemical analysis. X-ray spot size ranges from 10 m to 200 m.
An accuracy of 10% is typically quoted for routinely performed XPS atomic concentrations. For specific carefully performed and characterised measurements better accuracy is possible, but for quantification based on standard relative sensitivity factors, precision is achieved not accuracy.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.

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