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This video serves as an introduction to XPS, which is primarily analyzed through XPS data using software for quantification and chemical state information. Understanding the XPS technique is crucial for analyzing samples accurately. Energy spectra and the acquisition process are key aspects of XPS analysis, with an XPS spectrum representing an energy spectrum. This spectrum is obtained by sampling electrons arriving at a detector at different energy levels, allowing the creation of intensity histograms based on binding energy, which is related to the electronic configuration of atoms.