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in this video were going to consider features in casa xps that relate to the fitting of doublet piece in xps spectra the sample is germanium oxide on germanium and we have doublet peaks in the form of germanium 2p we also have germanium 3p these are both p orbitals and also there is a germanium 3d so theres lots of evidence within these data of chemical state and also doublet peak separation that varies depending on the core level that we analyze these germanium data are useful when we consider peak models because we have three different examples and they all have different characteristics so if i now display all three together we can see that weve got one example where the doublet pair separation is docHub and is far greater than the chemical state separation we have another example in the form of germanium 3d where the doublet pair separation is less docHub and indeed is quite difficult to identify from these data but the chemical state separation is docHub so we c