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XPS is performed by a radiating sample with x-rays of a specific energy the most common x-ray used for XPS lab based systems is aluminium however not all instruments are limited to aluminium and this spectrum is an example of a silver anode x-ray source which has produced x-rays twice the energy of the standard aluminium anode x-ray gun and as a result we are able to see core levels that are not available to the aluminium x-ray based systems the default element library in casa XPS has been defined for aluminium and magnesium x-ray guns and the reason these libraries are defined in terms of the x-ray guns is that the photon energy determines the relative sensitivity for photo emission Peaks so if you change the x-ray source and therefore the energy of the x-rays then these photo emission lines all appear with different relative intensities and therefore the library needs to present the correct relative sensitivity factors for the given x-ray source when a spectrum is displayed in the ac
